Coordination programming of photofunctional molecules.

Facile Synthesis of Photofunctional Nanolayer Coatings on Titanium Substrates

We developed a two-step chemical bonding process using photosensitizer molecules to fabricate photofunctional nanolayer coatings on hematoporphyrin- (HP-) coated Ti substrates. In the first step, 3-aminopropyltriethoxysilane was covalently functionalized onto the surface of the Ti substrates to provide heterogeneous sites for immobilizing the HP molecules. Then, HP molecules with carboxyl group...

Synthesis of novel photofunctional multinuclear complexes using a coupling reaction.

Various photofunctional metal complexes with functional groups, i.e. bromo and vinyl groups, were integrated into hetero-multinuclear complexes using the Mizoroki-Heck reaction. The obtained trinuclear complexes absorb a wide range of visible light and have a long excited state lifetime and the photocatalytic ability to obtain CO2 reduction.

Encapsulation of Stimuli-Responsive Molecules for the Preparation of Photofunctional Materials

Coordination of pricing and cooperative advertising for perishable products in a two-echelon supply chain: A bi-level programming approach

In this article the coordination of pricing and cooperative advertising decisions in one-manufacturer one-retailer decentralized supply chain with different market power for channel members is studied. The products are both perishable and substitutable. The problem is modeled as a nonlinear bi-level programming problem to consider both retailer and manufacturer decisions about prices and advert...

A photofunctional bottom-up bis(dipyrrinato)zinc(II) complex nanosheet

Two-dimensional polymeric nanosheets have recently gained much attention, particularly top-down nanosheets such as graphene and metal chalcogenides originating from bulk-layered mother materials. Although molecule-based bottom-up nanosheets manufactured directly from molecular components can exhibit greater structural diversity than top-down nanosheets, the bottom-up nanosheets reported thus fa...